블로그 이미지
Morning lark

카테고리

분류 전체보기 (1800)
Fuel Cell (838)
New Energy (837)
Energy Storage (6)
New Biz Item (2)
Total
Today
Yesterday
  • Sinopec has inaugurated its first large-scale research facility in Qingdao, Shandong Province, for producing hydrogen directly from seawater, marking a significant advancement in green hydrogen technology.
  • The facility efficiently converts seawater into hydrogen using green electricity from solar power, potentially revolutionizing the energy sector by utilizing a more sustainable and abundant water source.

China has taken a significant step forward in the renewable energy sector with the completion of a novel hydrogen production project that utilizes seawater. This first-of-its-kind factory-scale research initiative, based in Qingdao, Shandong Province, is spearheaded by Sinopec and employs direct seawater electrolysis coupled with green electricity.

The project boasts an impressive production rate of 20 cubic meters of hydrogen per hour. It harnesses green electricity generated by the offshore photovoltaic power stations of Sinopec Qingdao Refining & Chemical Co., Ltd., thereby integrating renewable energy sources like solar power into its operations.

The method involves splitting seawater into hydrogen and oxygen through specialized electrolyzers. This breakthrough addresses one of the main challenges previously associated with seawater electrolysis: the corrosion of electrolyzers due to saltwater and other impurities. Sinopec reports that this issue has been successfully tackled using "specially designed key equipment and unique processes."

The green hydrogen produced is then channeled into Sinopec’s pipeline network for various applications, including refining operations and as a fuel source for hydrogen-powered vehicles. This innovative approach not only facilitates the storage and transport of hydrogen but also contributes to the conservation of freshwater resources.

This project is a critical development in the hydrogen energy sector, offering a sustainable alternative by utilizing an abundant natural resource — seawater — thereby reducing reliance on freshwater sources. It stands as a testament to China's commitment to advancing green technology and sustainable energy solutions.

 

China Launches Pioneering Seawater Hydrogen Facility

 

Posted by Morning lark
, |

Technological advancements, policy interventions, and market shifts are shaping the future of green hydrogen in the global race to decarbonize. Here are four key points about its current state and the steps needed to unlock its full potential.

 

Like many in the green energy space, LONGi Green Energy Technology Company is ready to figure out whether green hydrogen—a potential source of renewable energy—can actually be a viable solution in society’s race to decarbonize.

In recent years, top decision makers at LONGi, a massively successful solar power company founded in 2000, have seen the company’s profitability slashed by plunging solar power prices and have determined that the firm’s hyperfocus on solar modules should expand to include a diversification into new growth areas. As such, in 2021, LONGi launched LONGi Hydrogen Energy Technology Company to manufacture green hydrogen equipment. The new arm’s first product was an alkaline water electrolyzer, which uses electricity to split water (H2O) into hydrogen and oxygen in a process called electrolysis. When the process is powered by renewables, it yields green hydrogen, an energy source devoid of carbon emissions.

But it is early days for green hydrogen. By 2024, LONGi was the world’s largest manufacturer of electrolyzers, and yet its green hydrogen equipment business generated a scant 1% of the company’s total revenues. In fact, green hydrogen accounts for less than 1% of all hydrogen produced, over 98% of which is still derived from natural gas. Overall, hydrogen represents a tiny slice of the world’s energy market, accounting for less than 1% of the global energy mix.

And yet, plenty of energy experts agree that green hydrogen can’t be discounted. Hydrogen has been called the Swiss Army knife of decarbonization because of its adaptability to a range of high-emitting areas across industry, power, heat, and some forms of transportation, such as marine fuels. It is also true, of course, that while Swiss Army knives can do lots of things, they aren’t exactly known for doing any one function particularly well.

Swiss Army knives shine, when there is a lack of alternatives—as may well be the case with green hydrogen. The business case will work for applications, where there are few viable alternatives.

Two of the biggest barriers to the expansion of green hydrogen have been its relatively high price—due mostly to the cost of electrolyzers and the renewable energy to power them—as well as infrastructure and compatibility problems with current power systems. What’s clear, and what adds to the uncertainty surrounding the space, is that the scale-up of green hydrogen will be heavily dependent on policy support.

Thanks to its relevance to many otherwise hard-to-abate sectors, global demand for hydrogen is projected to increase significantly in the coming decades, from 125 million tonnes (Mt) per year in 2030 to over 500 Mt by 2050. If demand does indeed track this steep upward path, it will require a dramatic scale-up in production—and oil majors and utilities are taking note. Saudi Aramco acquired a 50% equity stake in Blue Hydrogen Industrial Gases Company in 2024; the year prior, the utility company NextEra Energy announced a plan for full decarbonization that includes converting 16,000 megawatts of natural gas generating units to run on green hydrogen. The year before that, British oil and gas company BP acquired a $36 billion stake in what is now the Australian Renewable Energy Hub, which will produce 1.6 Mt of green hydrogen per year upon completion.

Then there is low-carbon steelStegra, formerly known as H2 Green Steel, is expected to complete the world’s first full-scale low-carbon steel plant by 2026. Since Stegra’s announcement, over a dozen other companies have announced their own intentions to produce over 40 Mt of low-carbon steel by 2030 in Europe alone.

Whether or not green hydrogen’s rise will meet these projections and ultimately play a central role in helping the world achieve decarbonization will depend upon more than whether existing technology can scale up. Much more work remains to be done in the space to develop new technologies, address infrastructure and compatibility issues, and formulate policies that can effectively jump-start a flow of hydrogen energy that becomes progressively greener as the years pass—not less so. 

Read on for four key points about the current state of green hydrogen development and where it needs to go from here.

Key Point No. 1: Incorporating hydrogen into the energy system is not a fanciful, futuristic idea—it’s already being done. Still, plenty about hydrogen and its use needs to change.

Today, hydrogen is commonly used as an input in petroleum refining, where it acts to break apart complex hydrocarbons and remove impurities. Most of the hydrogen used for this purpose, and others, is produced from natural gas, a process that releases carbon dioxide. 

Hydrogen made this way—from natural gas, with CO2 as a byproduct—is commonly known as grey hydrogen, which describes nearly all hydrogen production today, representing over 98% of the current hydrogen market.

Blue hydrogen, though it’s produced in the same way, earns a different color-coded designation because the carbon dioxide emitted through its production is captured and stored or utilized. Green hydrogen, on the other hand, is produced without using natural gas, whereby water is electrolyzed to split hydrogen from oxygen—releasing no carbon in the process. 

However, while the benefits of green hydrogen for the climate are obvious, the economics are less so. 

Green hydrogen is by far the most expensive of these variations to produce. Grey and blue hydrogen benefit from the relatively lower costs of fossil fuels, with grey hydrogen averaging between $1 and $3 per kilogram and blue running between $2 and $5 per kg (with costs inflated by the costs of carbon capture and utilization or storage, or CCUS). In comparison, truly green hydrogen commands at least double those prices: an average of between $4 and as much as $12 per kg, due to the costs of electrolyzer technology and renewable energy prices. (Powering electrolyzers with electricity from the grid is cheaper yet also not truly green, as the electricity mix on the grid typically is not.)

The upshot is, if green hydrogen is to ramp up quickly enough to become a significantly larger share of hydrogen production, its cost must come down. An open question remains as to how innovations in electrolyzer technology and renewable energy deployment, alongside strategic policy interventions, can bring this about—and whether the market is sufficiently motivated to figure it out. 

Key Point No. 2: Distinct technology pathways for green hydrogen are emerging—and each brings its own challenges and upsides.

Given that electrolyzers are the technology at the heart of green hydrogen production, it’s no surprise that the particularities of different electrolyzers have distinct implications for its ramp-up.

The alkaline water electrolyzer (AWE) currently dominates the market, with a roughly 60% share. AWEs achieve electrolysis using nickel electrodes, making them cost effective and durable. They are also the type currently manufactured by LONGi. At present, these electrolyzers are by far the least expensive on the market. However, they come with a major drawback: They require continuous electricity supplies for optimal production, ruling out dependence on the most widely available types of renewable energy.

Proton exchange membrane (PEM) electrolyzers, on the other hand, do better with intermittent renewable energy sources like solar and wind energy. Thanks to this advantage, PEM electrolyzers command about 30% market share, despite being far more expensive than their AWE counterparts.

But PEM electrolyzers present another hitch: They perform water electrolysis with solid polymer membranes and precious metal electrodes, and some of the metals required, like iridium, are in short supply. If PEM is to become a more promising source of electrolysis, new research and innovation will be required to tweak the technology and bring down its costs.

A third form of electrolyzer, anion/hydroxyl exchange membrane (AEM/HEM), accounts for a much smaller slice of the market, though many believe it’s a promising direction because the required materials—typically nickel, instead of titanium for PEM—are more common than those required by PEM. Unfortunately, this variation also comes with lower durability than other electrolyzer technologies, which means that, once again, more innovation is needed.

A fourth type is the solid oxide electrolyzer (SOEC), currently a tiny slice of the market, in part because of high capital investment costs and the high temperatures required. It is particularly viable for specific use cases such as industrial processes with high amounts of excess heat.

The distinctions between these four electrolyzer technologies point to manifold possibilities when it comes to separating hydrogen from oxygen—and also the often-devilish details that will need to be worked out, no matter which path is chosen. 

Key Point No. 3: Hydrogen promises to help decarbonize some otherwise hard-to-abate sectors, including steel and shipping.

The largest driver of current low-carbon hydrogen demand is the chemicals industry. Hydrogen and nitrogen are the two key ingredients needed to produce ammonia via the Haber-Bosch process. Future growth for (green) hydrogen is expected to come from other industrial sectors like steel and transport, especially shipping.

Some also see green hydrogen as key in decarbonizing long-haul road transport and aviation. Hydrogen fuel cell electric vehicles may prove superior to full electrification for long-haul trucking thanks to faster refueling, better ranges, and the fuel’s lighter weight. However, fuel cell technology will need to compete with ever-cheaper battery technologies and a concerted push for full-on electrification of road transport.

In the shipping sector, hydrogen in the form of liquid hydrogen or synthetic fuels can fuel ships directly, though the fuel’s lower energy density in this form makes transport on ships more difficult and requires carriers, like ammonia. 

Low-carbon hydrogen also shows some promise in aviation, with Rolls Royce and Airbus experimenting with hydrogen engines and planes. One key challenge preventing rapid uptake in this space, as in so many others, remains high costs.

Key Point No. 4: It’s crucial that policymakers around the world clearly and thoughtfully address a pressing question: What, exactly, constitutes green hydrogen?

Given green hydrogen’s market hurdles, it’s fair to say the fuel’s success currently depends on well-crafted political subsidies, tax credits, and financial initiatives. 

Many governments are acting accordingly: Over 30 jurisdictions, representing roughly 80% of energy-related carbon emission, have adopted national hydrogen strategies, with the European Union and the United States currently in the lead. Both sets of governments are backing research, development, and demonstration projects, offering grants and tax incentives, and establishing standards for large-scale hydrogen projects.

This last piece—standard setting—is crucial: What constitutes green hydrogen and is therefore eligible for generous tax credits and other support?

Three often-mentioned criteria are that green hydrogen must prove itself to be new (meaning brand-new installations of wind, power, or other renewables must be powering the projects); nearby (ensuring hydrogen projects are close to their suppliers of clean energy); and matched quickly with demand (hydrogen should be produced in line with when its renewable electricity is produced—when the sun is shining or the wind is blowing—so it’s not drawing from dirtier sources of power).

Getting these criteria right, including tax credits and other government subsidies more broadly, will be key in efforts to help the green hydrogen industry achieve its decarbonization potential.

 

Greening Hydrogen: Challenges, Innovations, and Opportunities

 

Posted by Morning lark
, |

概要

  1. NIMSの研究チームは、水電解装置用の電極触媒の劣化を、短時間の実験で高精度に予測できる手法を開発しました。天気予報でも使われるデータ同化という手法を組み合わせることで、約900時間で急速に劣化する材料を、300時間の実験結果から正確に予測することに成功しました。劣化予測が高速化され、さまざまな触媒材料の劣化の比較が容易となることで、劣化の仕組みの解明が進み、高効率かつ安価で寿命の長い触媒材料の開発が加速することが期待されます。
  2. 持続可能な社会構築に向け、二酸化炭素を出さずに水素を製造できる水の電気分解装置の大規模導入が求められています。装置を高効率で長期間運用するには、電極触媒の劣化を抑えることが極めて重要です。しかし電極触媒の耐久性評価には、通常数千時間、場合によっては数万時間という長い時間を要するため、短時間で電極触媒の劣化を正確に予測できる信頼性の高い手法の開発が強く求められていました。
  3. 今回、NIMSの研究チームは、電極触媒の劣化予測にデータ同化と呼ばれる手法を組み合わせました。データ同化とは天気予報でも使われる手法で、実験結果にばらつきがあることを想定し、一定数のフィッティング計算を繰り返してパラメータの最適化を行います。研究では、触媒の表面が溶出などで劣化する様子をシンプルな数理モデルで表現し、まずは数時間の劣化試験によく当てはまることを確認しました。次に長時間(約900時間)分のデータをもとに、データ同化を用いて劣化予測を行ったところ、わずか300時間分の実験データを使ってパラメータ推定を行うことで、900時間後の劣化を4%の誤差で予測することに成功しました。
  4. 今後はアルゴリズムを改良してより短時間での予測を目指すとともに、触媒材料が劣化するメカニズムの解明を進めます。それにより、材料の高特性化を実現させ、カーボンニュートラル実現のための水電解装置の普及につなげます。
  5. 本研究は、文部科学省におけるデータ創出・活用型マテリアル研究開発プロジェクト事業(JPMXP1121467561)の一環として、エネルギー・環境材料研究センター電気化学エネルギー変換チームのMiao Wang(別ウィンドウで開きます) NIMSポスドク研究員と坂牛 健(別ウィンドウで開きます) チームリーダー、および若手国際研究センター(ICYS)の石井 秋光(別ウィンドウで開きます) ICYS研究員によって行われました。
  6. 本研究成果は、2024年12月9日に米国化学会誌ACS Energy Letters(DOI: https://pubs.acs.org/doi/10.1021/acsenergylett.4c02868)のオンライン版に掲載されました。
  7. 天気予報の手法で革新 ! 水電解電極材料の劣化を短時間で予測 | NIMS
 

天気予報の手法で革新 ! 水電解電極材料の劣化を短時間で予測 | NIMS

NIMSの研究チームは、水電解装置用の電極触媒の劣化を、短時間の実験で高精度に予測できる手法を開発しました。

www.nims.go.jp

 

Posted by Morning lark
, |

東京科学大学は、貴金属や希少金属を使用しない水電解酸素生成電極触媒を開発した。層間にフッ化物イオンが局在する層状ペロブスカイト構造のPb3Fe2O5F2が、高い酸素生成活性を示すことを発見した。

東京科学大学は2024年12月5日、貴金属や希少金属を使用しない水電解酸素生成電極触媒を開発したと発表した。鉛と鉄(Fe)に酸素(O)とフッ素(F)が複合した酸フッ化物のPb3Fe2O5F2が、通常型ペロブスカイトPbFeO2Fよりも高い酸素生成活性を持つことを発見し、そのメカニズムを解明した。

 Pb3Fe2O5F2は層状ペロブスカイト構造で、同一相内に複数種のアニオン(陰イオン)を含む複合アニオン化合物だ。層間にフッ化物イオンが局在する。

 研究グループは、フッ化物イオンの高い電子求引性が特定の結晶面上にある触媒活性点Feの電子状態に影響を及ぼし、酸素生成活性を高めることを突き止めた。

(a)Pb3Fe2O5F2、PbFeO2Fの結晶構造。(b)双方の原料α-Fe2O3を用いて作製した電極に対する電流-電位曲線と(060)結晶面でのフッ素による活性向上に関する概要図。電流-電位曲線では、立ち上がる曲線は酸素生成に伴う酸化電流を示しており、より急峻な曲線は高い酸素生成活性を表す[クリックで拡大] 出所:東京科学大学

 水から酸素と水素を生成する水電解技術は、カーボンニュートラルを推進するためのエネルギー変換技術として注目されている。しかし、既存の電極触媒は、貴金属や希少金属を組み込むことで活性向上が図られており、材料の供給リスクやコスト面が懸念されていた。

 Fは、安価で資源制約が小さいpブロック元素であることから、低コストかつ高活性な酸素生成電極触媒の開発が期待される。

 

レアメタルを使用せず、酸フッ化物を用いた水電解酸素生成電極触媒を開発:研究開発の最前線 - MONOist

 

https://monoist.itmedia.co.jp/mn/articles/2412/26/news037.html

 

monoist.itmedia.co.jp

 

Posted by Morning lark
, |