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 アルカリ水電解(AWE)やプロトン交換膜(PEM)に比べて、開発メーカーが極端に少なかったのがアニオン交換膜(AEM)形水電解装置である。ただし、技術的にはAWEとPEMのいいとこ取りとも言われ、優れた点が多い。特に、触媒に高価なレアメタルが不要で、コストをPEMに比べて大幅に下げられる可能性がある。

 課題は耐久性の確保で、セルスタックはまだPEMの数分の1程度の時間しか使えないもようだ。この点についてこれまで唯一、製品化していたドイツEnapterの戦略は、電気自動車(EV)を刷新した米Tesla(テスラ)のそれに似ている。つまり、非常に小さなモジュールを多数使い、制御していくことだ(図1)。

図1 Enapterは超小型モジュール戦略を採用
世界で初めてAEM形水電解装置を製品化したEnapterのシステム拡大戦略。最小構成では、セルスタックと補器を寸法が482mm×635mm×266mmと、机に載るほど小型の筐体に収めた(a)。規模拡大時は、セルスタックの数を増やす一方、補器を共通化する(b)。セルスタック420個から成るシステムも開発中だ(c)(出所:(a)は日経クロステック、(b)、(c)はEnapter)
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 具体的には、MW級の大型装置でも、出力が0.5Nm3/時と手で持てるほど超小型のセルスタックを多数使う設計にした。こうすると、セルスタックが1つ壊れても制御で全体には影響が出ないようにでき、交換も容易になる。Enapter製品の輸入代理店の1つで機械系商社兼システムインテグレーターの三國機械工業 環境プロジェクト本部 プラント営業部長の三田逸郎氏は、「数を量産することが、コスト低減への早道という考えもEnapterにはあるようだ」という。

 三田氏によれば、あまり知られていないAEMの特長として、カソード側に漏れてくる水がPEMに比べて大幅に少ない点を挙げる(図2)。PEMでは水が漏れるのを防ぐ仕組みがないのに対し、AEMでは隔膜を透過してきた水がカソードで即座に分解されるからのようだ。

図2 AEMは乾燥器が小さくてよい
AEM形水電解の特長の1つは、水がカソード側に漏れにくい点。PEMでは水はプロトンの単なる運び役で、カソードから多くが漏れ出てしまう。一方、AEMでは、カソードに到達した水は即座に還元され、水素の形で発生すると同時に、OH-はアノードに向かう。結果、漏れてくる水は少ない。これで、水の大型タンクや大型の乾燥器(ドライヤー)が不要になり、システム全体のコストやランニングコストが低減する(出所:日経クロステック)
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部材では激しいシェア競争も

 最近は、Enapterに続く装置メーカーや部材メーカーも複数登場してきた。例えば、カナダCipher Neutronは2023年8月以降、AEM形の製品を幾つかのグリーン水素プロジェクトに納入し始めた。ただし、現時点では装置の規模は10kWと小型だ。特長は、PFASフリーであることだとする。

 また、第2部で紹介した、工場の規模が計画では15GWと現時点で世界最大の米EvolOHもAEMを採用した。

 AEM向け隔膜またはMEAでは、実はトクヤマやドイツFumatechが以前から製品を出荷している。最近はこれに、米Dioxide MaterialsやドイツEvonik Industriesも参戦。さらに、上述のようにパナソニックも、NiFe-LDHをアノードに用いたMEAで参戦する(図3)。近い将来、競争が急速に激しくなりそうだ。

(a)アノードにNiFe-LDHを用いたAEM用MEA
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図3 パナソニックはAEMにも参戦
パナソニックのAEM膜(a)。AWEと同様、アノードの触媒にNiFe-LDH(Layered Double Hydroxides)を利用。隔膜にはAgfa-Gevaertの競合品を用いた。従来のIrO2触媒に比べて低い過電圧を実現できるという(b)(出所:(a)はパナソニック、(b)は同社の資料に日経クロステックが加筆して作成)
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後発の水電解技術AEMにも参戦続々、耐久性克服なら主役級

 アルカリ水電解(AWE)やプロトン交換膜(PEM)に比べて、開発メーカーが極端に少なかったのがアニオン交換膜(AEM)形水電解装置である。ただし、技術的にはAWEとPEMのいいとこ取りとも

xtech.nikkei.com

 

Posted by Morning lark
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Shifting to mass production is key to producing competitive renewable hydrogen. Partnering with Air Liquide, Siemens Energy is scaling production of electrolyzers using standardization and automation aiming to cut the cost of renewable hydrogen down to size. It’s a development that sits at the heart of the energy transition.

Hydrogen has a key role to play on the road to net zero.

Acting as an energy vector, a storage medium, a raw material for synthetic liquid fuels, and as a gaseous fuel able to address emissions from some of the hardest to abate industrial sectors like steel, chemicals, heavy transport and power generation, hydrogen is vital. Unfortunately, so-called green hydrogen generated using renewable energy is currently too expensive to produce. For this reason, the hydrogen market today is dominated by steam reformation of natural gas, it’s essentially a fossil fuel. However, the imperative of climate change has been amplified by other factors such as security of energy supply concerns that have been greatly increased by the war in Ukraine, for example. This has emphasized the importance of developing a cost-effective renewable hydrogen industry and prompted an acceleration of the market.

Despite the growing interest in renewable hydrogen, the cost has remained an impediment to widespread adoption and displacement of the fossil-fuel derived hydrogen that dominates the current market. The joint venture between Siemens Energy and Air Liquide aims to producing industrial volumes of green hydrogen available bringing economies of scale through the mass production of electrolyzers. The move will not only secure access to electrolyzer capacity but crucially get them at the right price without compromising on safety, quality, and reliability.

Hydrogen Scaling production

Scaling renewable hydrogen production to industrial volumes starts with developing a supply chain that can meet global demand and deliver thousands of megawatts of electrolyzer capacity needed every year. By combining their expertise and efforts, Siemens Energy and Air Liquide intend to do just that with the launch of a gigawatt-scale factory in Berlin. The plant, which heavily relies on automation and robotics to produce electrolyzers in bulk, will initially produce 1 GW of Siemens Energy’s Silyzer 300 Proton Exchange Membrane (PEM) electrolyzer stacks annually. The PEM technology offers a high degree of efficiency and is ideally suited to the variable output that is typical of renewable energy resources. Furthermore, under current plans, this production capacity will increase by at least 1 GW per year, reaching a hefty 3 GW annually by 2025 with a potential for more. In a second step the electrolyzer arrays are being assembled locally, e.g. in the Siemens Energy manufacturing site Muelheim, or in external workshops in the Czech Republic or France or close to future project sites. 

Production at the Huttenstrasse facility, located in Berlin’s Moabit district, has just started. The site has so far been known particularly to produce hydrogen-capable gas turbines. The new production line occupies some 2000 m2. The joint venture expects several benefits, alongside the economies of scale that are translating into a reduction in costs, as has been previously witnessed with renewable energy technologies like wind and solar PV. For example, by partnering with Air Liquide – which is taking a 25.1% equity stake in the JV alongside Siemens Energy’s 74.9% – the gigawatt-scale factory already has a strong business case with a reliable partnership that secures sustained, competitive and reliable product off-take. Both partners able to meet electrolyzer demand arising from their individual portfolios of hydrogen projects.

In addition, in partnering with Air Liquide, Siemens Energy has a strong relationship with a company that has vast experience and deep knowledge of the processes to produce the hydrogen and oxygen, such as hydrogen liquefaction, methanol synthesis, ammonia synthesis, or ammonia cracking. 

It is key to long-term success that the Siemens Energy electrolyzer fits the needs of the downstream processes and can also be optimized to better meet those needs in the future. Air Liquide is already working with Siemens Energy electrolyzers deployed at its site in Oberhausen, Germany, in the flagship Trailblazer project. This allows both partners to gather detailed knowledge on how to integrate electrolyzers into an existing plant configuration and learn how to operate the system in combination with existing assets, such as compression and off-take. Sharing know-how, risks and opportunities, the partners aim to rapidly accelerate the transition to affordable renewable hydrogen.

One of the first projects to use stacks from the Berlin multi-gigawatt factory is Air Liquide’s Normand’Hy electrolyzer project. With a capacity of 200 MW, it is the one of the largest PEM electrolyzers currently under development.  This project will apply the learnings from Air Liquide’s Trailblazer project in Oberhausen. Other renewable and low-carbon hydrogen projects are also earmarked for development in the Netherlands and elsewhere using the Berlin-produced stacks.

Continuing to cut costs

Within the framework of the partnership, Air Liquide and Siemens Energy have also agreed to dedicate R&D resources to the development of the next generation of electrolyzer technologies. Further efficiency improvements are anticipated, especially given the progress to date.

Siemens Energy started developing hydrogen electrolyzer technology more than a decade ago with a small lab-scale PEM. A commercial product, the Silyzer 200, followed in 2015 with a rated capacity of around 1.25 MW. Although the Silyzer 200 represented a major jump in capacity it was still not suitable for large-scale hydrogen production. That changed with the launch of the Silyzer 300 which has more than 10 times the amount of hydrogen output than the 200 version. Indeed, the Silyzer portfolio scales up by factor 10 every four or five years and sees substantial improvements in efficiency with each generation.

Simultaneously, manufacturing processes have also evolved, from the hand-built Silyzer 100 and 200 to exploring the development of automated manufacturing equipment and implementation of larger scale machines with the launch of the 300. Siemens Energy is also developing manufacturing equipment together with external companies, removing manual processes and increasing automation. 

The focus in Berlin is mass production of the existing stacks and a huge step up in production volumes. Increasing production with a factor of 100, within four or five years is only possible in a fully automated large-scale mass production plant of the kind that is being developed in Berlin. Solid investment in manufacturing capacity is enabling the supply chain to invest in capacity growth with confidence too, ramping up from single piece production to mass production in line with stack manufacturing volumes. 

In order to cut the specific cost of hydrogen, while mass production of the stacks will take place in Berlin, assembly of the final product will take place closer to the project sites. The Silyzer product contains 24 PEM stacks but built around it are the various ancillaries that are needed for the stacks to operate. These items include the manifolds for the gas, the cooling system, the gas separation system, and the electrical connections among others. In Germany, this stage of assembly will take place at Mülheim but that will change depending on the location of the final project. For the Air Liquide Normand’Hy project, for example, Siemens Energy will work with a French company to produce the skid-mounted electrolyzer array. This approach of working with external partners close to where the final customers are based is key to match the market needs.      

   

Building a hydrogen ecosystem

Reasonably priced and affordable renewable hydrogen derived from renewables is a prerequisite for achieving net zero carbon. It is therefore key for our future. By moving into large-scale mass production, the Air Liquide-Siemens Energy partnership is taking a big step towards a cost-effectivehydrogen economy using automation  and standardization to build economies of scale. At the same time as volumes soar, demand for the electrolyzer business is also rapidly accelerating, rising from approximately 50 or 60 stacks five years ago and increasing by a factor of 10 this year and another factor of 5 to 10 anticipated over the next few years. By fostering a global ecosystem for electrolysis and hydrogen technology, the joint venture is engineering access to industrial volumes of cost-competitive renewable hydrogen. The challenge is global warming, part of the solution is a gigawatt-scale factory

 

https://www.hydrogenfuelnews.com/pump-up-the-volume-hydrogen-hits/8561607/?awt_a=1jpsU&awt_l=YbiARn&awt_m=i3Hef1tId85DlsU

 

Pump up the volume: Hydrogen hits the big time

Shifting to mass production is key to producing competitive renewable hydrogen. Partnering with Air Liquide, Siemens Energy is scaling production of electrolyze

www.hydrogenfuelnews.com

 

 

 

 

 

Posted by Morning lark
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Bloom Energy electrolyzer accelerates the future of hydrogen production in south Korea.

Bloom Energy (NYSE: BE) announced the first international deployment of its high temperature solid oxide electrolyzer.

The successful 130 kilowatt (kW) installation in Gumi, South Korea, further propels Bloom Energy’s efforts to enable a hydrogen-fueled economy following the commercial launch of the Bloom Electrolyzer in 2021.

Bloom’s high-temperature electrolyzer is operating at its designed high efficiency, producing hydrogen onsite more efficiently than low-temperature PEM and alkaline electrolyzers. Because it operates at high temperatures, the Bloom Electrolyzer requires less energy to split water molecules and produce hydrogen.

As electricity accounts for up to 80 percent of the cost of hydrogen from electrolysis, using less electricity increases the economics of hydrogen production and helps bolster adoption.

Fully operational at the Bloom SK Fuel Cell center in South Korea since January 2022, this new demonstration is testing electrolysis efficiency using water as an input in intermittency mode. The Bloom Electrolyzer is effectively and efficiently operating in daily cycles, demonstrating its ability to pair with intermittent renewables, such as solar and wind.

In production, the Bloom Electrolyzer is expected to operate at 46 kilowatt hours (kW-hr) per kilogram of hydrogen (kg H2) output with water as its input. When steam is used, the electrolyzer requires even less electricity, expected to operate at 40.4 kW-hr/kg H2, driving further efficiencies.

Deia Bayoumi, vice president, global product management, Bloom Energy, said:

The successful deployment of our electrolyzer internationally is a testament to the confidence it has garnered to create viable pathways to achieving a net-zero, hydrogen-fueled future.

“This marks a critical step in our mission to transform the global energy landscape and enable the hydrogen economy.”

The project aligns with South Korea’s efforts to decarbonize its energy system and become a global leader in the hydrogen economy in the coming decades. Investing heavily in new technologies and infrastructure to spur the production and adoption of the carbon-neutral fuel, South Korea aims to replace fossil fuels with hydrogen as its chief power source by 2050, according to the Ministry of Trade, Industry, and Energy.

With the capacity to scale hydrogen production rapidly, Bloom Energy and SK ecoplant are well-suited to drive South Korea’s energy transition forward.

Seoung-hwan Oh, vice president, hydrogen business, SK ecoplant, said:

A significant milestone in our successful partnership with Bloom Energy, this latest collaboration is a testament to our shared vision to transform South Korea’s energy landscape and unlock new value through innovation.

“Bloom Energy’s technology has demonstrated unparalleled performance and efficiency, further establishing us at the forefront of South Korea’s clean energy market.”

Highly flexible, the Bloom Electrolyzer offers unique advantages for deployment across a broad variety of hydrogen applications, using multiple energy sources including intermittent renewable energy and excess heat. Its modular design also makes it ideal for applications across gas, utilities, nuclear, wind, solar, ammonia and heavy industries. Thanks for staying up to date with Hydrogen Central.

For more information about the Bloom Electrolyzer and the company’s commitment to a zero-carbon future, visit: www.bloomenergy.com/bloomelectrolyzer.

About Bloom Energy

Bloom Energy empowers businesses and communities to responsibly take charge of their energy. The company’s leading solid oxide platform for distributed generation of electricity and hydrogen is changing the future of energy.

Fortune 100 companies around the world turn to Bloom Energy as a trusted partner to deliver lower carbon energy today and a net-zero future. For more information, visit www.bloomenergy.com.

Highlights:

  • Bloom Energy’s first international electrolyzer deployment showcases pathways to produce clean, low-cost hydrogen at scale to unlock South Korea’s net-zero future

READ the latest news shaping the hydrogen market at Hydrogen Central

Bloom Energy Electrolyzer Accelerates the Future of Hydrogen Production in South Korea, SAN JOSE, Calif., April 6, 2022 

Posted by Morning lark
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