블로그 이미지
Morning lark

카테고리

분류 전체보기 (1950)
Fuel Cell (857)
New Energy (961)
Energy Storage (6)
New Biz Item (2)
Total
Today
Yesterday

TOPPANホールディングスが次の事業の柱に見据えるのが、水素だ。創業以来培ってきた印刷技術を、水電解装置や燃料電池向けの電極製造に生かす。およそ19年かけて開発した電極製造技術「ダイレクトコーティング」は、既存の転写方式と比べて触媒層と電解質膜の密着性が高く、優れた出力特性と耐久性を示すという。

 この方式で製造した触媒層付き電解質膜(Catalyst Coated Membrane、CCM)、及び膜電極接合体(Membrane Electrode Assembly、MEA)の販売を2023年8月に開始し、水素市場への参入を果たした。開発を率いた谷脇和磨氏にこれまでの経緯や今後の展開を聞いた。

およそ20年前の2004年に検討が始まったと聞いている。深刻化する地球温暖化を抑えるべく当社のコア技術を生かして何か貢献できないかと考え、TOPPANが着目したのが水素エネルギーだった。はじめは、研究テーマに暗中模索する時期が長らく続いたそうだ。

 2012年に私がプロジェクトに加わり、水素社会の実現に向けて改めて方向性を議論した。その結果、将来は燃料電池車(FCV)が普及すると予想して、FCV向けのMEA加工の開発に舵(かじ)を切った。

 

TOPPANが新事業に水素、19年間極秘で進めた電極開発 | 日経クロステック(xTECH) (nikkei.com)

 

TOPPANが新事業に水素、19年間極秘で進めた電極開発

 TOPPANホールディングスが次の事業の柱に見据えるのが、水素だ。創業以来培ってきた印刷技術を、水電解装置や燃料電池向けの電極製造に生かす。およそ19年かけて開発した電極製造技術

xtech.nikkei.com

 

Posted by Morning lark
, |

In addition to the cost of electricity, the price of hydrogen depends largely on the up-front investment cost of the electrolyzer. The lower the full-load hours, the greater the impact. Analyst BloombergNEF (BNEF) sees a number of different possible pathways for the market to develop.

MARCH 21, 2024

All electrolyzers have a technology-specific stack at their center, in which water is split into hydrogen and oxygen. This consists of carefully layered, gas-tight, welded bipolar plates and plastic membranes – among the main cost factors in every electrolysis plant. Xiaoting Wang, an analyst at BloombergNEF, spoke to 20 companies worldwide as part of the company’s “Electrolysis System Capex [capital expenditure] could drop 30% by 2025” study. This gave her an insight into the cost structure for 30 projects and made it possible to determine the price components for a 10 MW alkaline electrolysis plant in China in 2021, as an example.

The stack accounted for around 33% of the total costs, said Wang, with 40% of the costs coming from the other technical equipment, including power electronics, gas and liquid separation, and gas purification (see chart below). A further 27% of the costs were attributable to other project expense, such as civil engineering, equipment installation, and housing.

Chinese alkaline

The BNEF report stated a 10 MW alkaline system often consists of two stacks of 5 MW that deliver hydrogen at 16 bar. The manufacturer usually offers a complete solution with all accessories and installation. Chinese developers received such an offer in 2021 for as little as $303/kW – that is, a total of around €3 million ($3.2 million). This did not include the grid-connection fee, high-voltage transformers, or other “soft” costs such as expenses for development, approvals and financing agreements.

Wang said that the project costs in Western markets with domestically produced electrolyzers are around four times as high. Investment costs averaged €1,200/kW for alkaline electrolyzers and €1,400/kW for proton exchange membrane (PEM) electrolyzers.

Cheaper offers, such as €180/kW, from Peric for an 80 MW plant in China; or €521/kW, from Thyssenkrupp for a 2 GW plant in Saudi Arabia, do not include all project costs and are, therefore, not comparable. They do include electrolysis stacks, gas liquid separation and purification, and the water supply. However, power electronics and control cabinets are excluded.

Wang attributed this large price difference to low labor costs and the established supply chains in China, where manufacturers of electrolyzers can source materials and components at much lower prices than in the West. Thus far, the production of most electrolyzers is not automated. Chinese manufacturers were producing megawatt-scale electrolyzers for other industries before there was demand from green hydrogen producers, meaning they benefited from scaled production. Existing customers included manufacturers of polysilicon for photovoltaic cells.

The Bloomberg analysis, from September 2022, claimed that Western manufacturers could achieve similarly low costs. To do so, they would have to utilize highly automated production. Wang said she anticipates significant price reductions by as early as 2025 (see main chart above). Prices for 2021 also still included adequate margins for engineering, procurement, and construction (EPC) companies. Long-term development shows that prices for electrolysis projects will converge worldwide from 2035.

Western investors tend to entrust an EPC company with the handling of an entire project for a lump sum, and to rely on large, well-known companies. Such companies usually have little experience in the construction of electrolysis plants, however, so the safety premiums in the price of the overall offer are high. With increasing experience and the entry of specialized project planners, which leads to more competition, these surcharges should decrease.

Prefabricated containers

Equipment suppliers are also endeavoring to offer products that reduce the workload on the construction site, and thus cut costs. One trend that supports this is the development of containerized systems. This means that the various system components do not have to be assembled on site but are instead prefabricated in a factory, tested, and delivered to the intended location. This minimizes sources of error and reduces the deployment time of specialist personnel on site.

In an update to its market analysis, Bloomberg reported on offers for such container solutions for $1,000/kW. Industry insiders have even reported offers as low as $700/kW, said Wang. One such container solution was presented in a pv magazine Germany webinar in February 2023. The PEM electrolyzer from German supplier H-Tec has an output of 1 MW and produces 450 kg of hydrogen per day. Recordings of pv magazine webinars are available at pv-magazine.com/webinars.

Those who want to reduce costs by purchasing an electrolyzer from China need to consider that exported products are usually sold at a premium of around 20% to 30%, compared to prices on the domestic market, said BloombergNEF, meaning that development and project planning costs would still be higher. It is important to consider that choosing a Chinese brand to supply the core equipment could reduce a project’s chance of receiving local subsidies and could affect financing.

The first green hydrogen projects were, and still are, mainly designed to draw electricity from the grid, with the electrolyzers’ electricity consumption balanced monthly or annually against the suppliers’ renewable electricity generation. In this case, the technical disadvantage of alkaline electrolysis in terms of flexibility would not bother operators.

However, after 2030, most new green hydrogen projects will need to ensure an hourly match between power generation and power consumption for grid-connected electrolysis systems, which will lead to more off-grid projects being developed, said Wang. This trend is not only due to the need for a clearer definition of green hydrogen. A direct connection to renewables generation plants should also improve economic feasibility in the future. After all, using the grid to shift huge amounts of electricity will cost more in the future. Electrolysis with stable grid electricity will, therefore, not be able to produce cheaper hydrogen in the future than with solar and wind energy, with their low electricity generation costs.



Cost reduction

This is where PEM electrolyzers come into play. These can better follow the fluctuating electricity supply and also work efficiently in partial load operation or off-grid. However, this technology still needs to significantly reduce its dependence on expensive platinum group metals, especially iridium, in order to gain a dominant market share, said Wang. Plug Power, from the United States, and ITM Power, from the United Kingdom, use 200 grams to 300 grams of iridium per megawatt of capacity.

Current worldwide production of iridium is around seven metric tons per year. Even if the entire volume were used to produce catalysts for PEM electrolysis, this supply chain could only support a maximum of 35 GW per year. PEM can only dominate the green hydrogen market if manufacturers manage to significantly reduce the consumption of iridium per unit this decade or achieve an equivalent effect in parallel with improved metal recycling. Wang said Electric Hydrogen, a new United States-based manufacturer of PEM electrolyzers, has already reported using significantly less iridium than competitors.

There is also a chance that anion exchange membrane (AEM) electrolysis could replace PEM after 2030 because it does not use expensive metals. This means manufacturers must succeed in developing stacks that are suitable for large scale projects. Enapter is an AEM pioneer, building small stacks and assembling them into larger 1 MW units which are still small compared to other electrolyzers. California-based company Verdagy is just starting to sell 20 MW modules, each consisting of two 10 MW stacks.


More competition

The costs of Western products could initially fall by around 30% by 2025. In addition to technological progress, competition is also likely to increase. Manufacturers worldwide have announced a production capacity of 52.6 GW for this year while deliveries are optimistically only 5 GW, according to BloombergNEF’s forecast. In China, where there is already fierce competition for orders from project developers, manufacturers’ margins are small. In addition, developers hedge their risk against the manufacturer by paying only up to 85% of the agreed price on delivery and the rest once commissioning has been completed and performance is still good after 18 months.

The pressure is not yet as high on Western markets, as investors and project developers in Europe and the United States can reckon with relatively high subsidies. However, production capacities are also increasing here and factories need to be fully utilized. If Chinese manufacturers also seek their salvation in exports, it is foreseeable that the price war will increase in all markets.

Posted by Morning lark
, |
Yanmar and Amogy have entered into a Memorandum of Understanding (MoU) to integrate Amogy’s advanced ammonia-cracking technology into Yanmar’s hydrogen internal combustion engine (H2ICE). This collaboration seeks to pioneer a solution for decarbonising marine power generation.

The partnership will focus on combining Amogy’s technology with Yanmar’s H2ICE to provide low-cost hydrogen fuel. Amogy’s ammonia-cracking technology uses catalyst materials to break down ammonia into hydrogen and nitrogen at lower reaction temperatures with high durability, minimising heating and maintenance requirements. This integration promises a comprehensive clean energy solution for decarbonising marine power generation.

Furthermore, building on this joint research, both companies will explore the potential for collaboration in developing maritime hydrogen fuel cell systems.

“We are excited to work with Amogy on this innovative project,” said Ken Kawabe, Group Leader at Yanmar Research and Development Centre. “Our commitment to a sustainable future aligns perfectly with this collaboration, and we believe that integrating Amogy’s ammonia-cracking technology with our H2ICE has immense potential for decarbonising marine power.”

“As pioneers in sustainable energy solutions, we are thrilled to collaborate with Yanmar in exploring the integration of our cutting-edge ammonia-cracking technology with their hydrogen internal combustion engines,” said Seonghoon Woo, CEO at Amogy. “Collaboration is critical to advancing clean energy solutions and, together, we can overcome challenges and expedite sustainable progress in the marine sector.”

The collaboration between Amogy and Yanmar began in 2023 when Yanmar Ventures, Yanmar's corporate venture capital arm, invested in Amogy. Since then, both companies have been exploring opportunities to integrate their technologies.

Posted by Morning lark
, |

PGM-free Electrodes for AEM and Alkaline Electrolysis - Catrode®

With Latent Drives' innovative electrochemical treatment process, they activate stainless steel electrodes to make Catrodes® which combine both catalyst and electrode as one homogeneous part, without additional ingredients.
Catrodes are PGM-free (Platinum Group Metal) robust high-performance products.
The production process is developed for high volume mass production at realistic costs – reducing the capital costs of Green Hydrogen.
The Catrode is a Ni-Fe catalyst. First, the electrochemical surface area is increased then chromium is removed, and nickel is migrated and exposed on the surface of the stainless steel felt to produce a nickel iron catalytic surface layer.
The catalyst layer is formed on stainless steel felt which acts as both the Catalyst, Electrode and Gas diffusion layer combined.
Catrodes are 0.6mm thick with an active area of 200 cm² as standard but different thickness and areas could be treated as a custom request.
PGM free Catrodes performance in OER is comparable with state-of-the-art precious metal catalysts such as platinum and iridium and significantly surpasses the performance of nickel electrodes at a much-reduced cost.
Catrodes exhibit a stable performance below 1.58V RHE at 0.2A/cm2 at 50°C for 22 hours run in an ElyFlow test cell with an active area of 10 cm² compared to the overpotential of a commercially available Catalysed Nickel foam which reached 1.69V RHE.
The PGM-free Electrodes are designed to be run wet i.e. with liquid electrolyte in contact with the Catrode and membrane. Not intended for use with Nafion membranes.
Key features

Suitable for AEM and Alkaline Electrolysis
PGM-free (Platinum Group Metal) robust high-performance products
Developed for high volume mass production at realistic costs
Catrode is a Ni-Fe catalyst
Available in different thickness and areas as a custom request
Comparable with metal catalysts such as platinum and iridium and significantly surpasses the performance of nickel electrodes at a much-reduced cost
PGM-free Electrodes for AEM and Alkaline Electrolysis - Catrode®_2



Application areas

For alkaline water electrolysis, with either AEM or Zero Gap designs.
For use with Potassium Hydroxide (KOH) electrolyte in concentrations from 01.M to 5M.
Catrodes were developed to be used as anodes but can also be used as cathodes in an alkaline electrolyser.
Catrodes may also have potential to be used in batteries and fuel cell technology but after mutual collabaration with Latent Drive.
Use cases

Catrodes are being used as the combined gas diffusion layer and catalyst in a European electrolyser startup.
Catrodes in the form of treated stainless steel sheet is also being developed for a customer.
Contact us

Latent Drive is at the forefront of fuel cell technology innovation for novel applications. Interested? Please contact the vendor by filling in the contact vendor form.

Posted by Morning lark
, |

 

出光興産、東京大学、大阪大学、産業技術総合研究所は2024年7月4日、常温・常圧環境下でアンモニア(NH3)を空気中の窒素(N2)と水(H2O)と電力から連続的に合成する技術で、競合のアンモニア生成速度を20倍上回る世界最高性能を達成したと発表した(図1)。今後、2028年度までにシステムの規模を拡大すると同時に生産効率をさらに高める研究開発を進め、その後は社会実装に向けた開発をして、2032年度に1000トン/年規模のアンモニア生産を目指すとしている。

[画像のクリックで拡大表示]
図1 競合に対して約20倍のアンモニア生成速度を実現
報告例1は2020年、報告例2は2023年でいずれも中国科学院の研究者の論文(出所:出光興産)

 アンモニアは100年余り前にドイツで水素(H2)と空気(実際には窒素ガス)から合成する技術「ハーバー・ボッシュ(HB)法」が開発されたことで、低コストで量産できるようになり、それを肥料に用いることで食料の生産量が飛躍的に高まり、世界の人口の急速な増加につながった。ただし、HB法には、
(1)高温高圧を必要とし、結果として装置が超大型になる
(2)水素は別途、生産または調達する必要がある
(3)(2)の水素を生産する過程で、少なくともこれまでは大量の二酸化炭素(CO2)を排出していた
といった課題があった。

 こうした背景から、出光興産らは新エネルギー・産業技術総合開発機構(NEDO)のグリーンイノベーション基金事業の委託業務として、常温常圧でしかも、水素の生産や調達を必要としないアンモニア合成法の開発を進めている。

PEM形水電解システムの一部を流用

 システムの概要は図2の通りになる。まず、水素の代わりとしての水、そして窒素原子Nの供給源としての窒素ガスを電解セルスタックに投入する。この際、還元剤と、窒素分子の3重結合を切るための触媒も同時に投入する。

(a)システムの構成
[画像のクリックで拡大表示]
(b)実際のシステム
[画像のクリックで拡大表示]
図2 システムはPEM形水電解に似る
今回のアンモニア電解合成システムの構成(a)と、実際の実験システム(b)。研究者が手にしている黒いデバイスが電解セル。今後はこれをより大型にする計画だ(出所:(a)は出光興産の資料に日経クロステックが加筆、(b)は出光興産)

 この電解セルスタックは、水を電気分解するPEM(Proton Exchange Membrane)形水電解のセルスタックと、多くの部材や構造が共通する。PEM形水電解では、水をアノードで酸化してプロトン(H+)にした後、カソードで還元して水素を取り出す。

 今回の電解セルスタックでもアノードの役割はPEM形水電解と同じである。ただ、カソードでこのプロトンに加えて、水、及び触媒に配位した窒素原子Nなどをまとめて還元することでアンモニアを合成する。

世界をリードする2つのブレークスルー

 この開発では大きく2つのブレークスルーがあった。1つは、常温常圧の下で窒素分子の3重結合を切るための触媒の開発だ。これは東京大学 大学院 工学系研究科 教授の西林仁昭氏の研究チームが開発したモリブデン(Mo)を基にした触媒(図3)である。空気中の窒素を固定する根粒菌が持つ酵素「ニトロゲナーゼ」についての研究が端緒になっている。

図3 Mo触媒の例
東京大学の西林研究室が開発したMo触媒の化学式の例。最近はさらに改良が進んでいるようだ。tBuは、tertiary Butyl(出所:東京大学 西林研究室)

 

出光などが「世界最高性能」、常温常圧で水素不要のアンモニア合成 | 日経クロステック(xTECH) (nikkei.com)

 

出光などが「世界最高性能」、常温常圧で水素不要のアンモニア合成

 出光興産、東京大学、大阪大学、産業技術総合研究所は2024年7月4日、常温・常圧環境下でアンモニアを空気中の窒素と水と電力から連続的に合成する技術で、競合のアンモニア生成速度を2

xtech.nikkei.com

 

Posted by Morning lark
, |